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<div class="cbox-1-0 p_item"><div class="e_container-6 s_layout"> <div class="cbox-6-0 p_item"><h1 class="e_h1-10 s_subtitle"> 化工技術|1,4-環己烷二甲醇成本 </h1><div class="e_container-3 s_layout"> <div class="cbox-3-0 p_item"><p class="e_text-5 s_body"> 發布時間 </p></div> <div class="cbox-3-1 p_item"><P class="e_timeFormat-4 s_title">2022-06-29 17:39</P></div> </div><div class="e_richText-11 s_title"> <p> 環己烷二甲醇（CHDM）實現國產化生產后，生產成本高，銷售價格每噸接近3萬，高成本制約著應用，直接影響了下游產品性價比。</p> <p> <strong>1,4-環己烷二甲醇加氫合成</strong><br /> CHDM為白色蠟狀固體，是一種重要的有機化工原料，分子式為 C8H16O2，分子量為 144.21,有順式、反式兩種結構順式異構體熔點為 43℃，反式異構體 70℃， 1,4--環己烷二甲醇（CHDM）是涂料，油墨，膠黏劑，絕緣材料及一些特殊用途方面的飽和聚酯和不飽和聚酯的中間體，用途在于合成PCT、PETG、PCTG新型聚酯，產品具有良好的透明性、耐沖擊性、耐磨性和耐腐蝕性。</p> <p> CHDM主要由對苯二甲酸二甲酯（DMT）經兩步加氫反應制得，由DMT先苯環飽和加氫生成1,4-環己烷二甲酸二甲酯（DMCD），再通過酯基氫解經中間產物4-（甲氧羰基）環己烷甲醇（CMCHM）生成CHDM。</p> <p> <strong>化工技術1,4-環己烷二甲醇生產原料成本高</strong><br /> 為DMT經兩步不同的加氫反應生成，目前國內已經建設成的生產裝置都是DMT外購或進口，目前的市場價格下，生產1噸CHDM ,所需的DMT原料成本就占到1.4萬元</p> <p> 兩步加氫消耗的氫氣量大，由于DMCD和CHDM飽和蒸汽壓較低，氣相反應需要的氫氣循環量巨大，一般需要氫油摩爾比在600以上，巨大的氫氣循環量不僅大大增加能耗，而且限制產能，液相加氫生產CHDM，氫油摩爾比從氣相的600降低到80-200，雖然大幅減少了氫氣的循環量，但是目前，生產1噸CHDM氫氣消耗成本也要在3000元。</p> <p> 化工技術1,4-環己烷二甲醇催化劑成本高<br /> 環己烷二甲醇具有順式、反式 2 種異構體結構，反式比例結構較為對稱，晶格結構規整，晶格能高，具有較高的熔點，產品的耐熱性好，用于生產 PETG 等聚酯產品時，反式比例越高，聚酯耐熱性能越高，產品性能好，但是，對催化劑選擇性要求高，催化劑為貴金屬催化劑，如果催化劑選擇性不高，造成了催化劑成本高。<br /> 目前，工業DMT加氫工藝一定程度上降低了加氫操作壓力，但目標產物收率較低。因此，為了程度上減少催化劑用量、降低催化劑成本，需要開發高活性、高選擇性的新型催化劑，以降低 DMT 加氫的操作壓力、提高目標產物 DMCD 的收率，這是 DMT 加氫工藝發展方向。</p> </div><div class="e_container-12 s_layout"> <div class="cbox-12-0 p_item"><p class="e_text-13 s_title"> </p></div> </div><div class="e_websiteShare-8 s_list" needjs="true"> <div class="p_share" data-ename="分享容器" data-selectValue="1"></div> </div></div> </div></div> </div> <input type="hidden" name="propJson" 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為認真履行企業污染防治主體責任，做到嚴格自律，現做出如下承諾：一、自覺公開環境信息，不隱瞞、不欺騙，主動接受公眾和新聞媒體等社會監督；二、自覺遵守環境保護法律法規，做好污染治理設施以及在線監控設施運行管理。確保污染物達標排放，不偷排；確保在線監控數據設施數據真實，主動配合環境執法檢查。 </a> </p><hr class="e_line-16 s_line" /></div> </div></div> <div class="cbox-9 p_loopitem"><div class="e_container-10 s_layout"> <div class="cbox-10-0 p_item"><div class="e_container-18 s_layout"> <div class="cbox-18-0 p_item"><p class="e_text-12 s_title"> <a href="/news_detail/13413793.html" target="_self"> 擬列入浙江省危險廢物利用處置“白名單”企業(第一批)名單 </a> </p></div> <div class="cbox-18-1 p_item"><P class="e_timeFormat-20 s_summary">2022-07-19</P></div> </div><p class="e_text-17 s_summary"> <a href="/news_detail/13413793.html" target="_self"> 根據《國務院辦公廳關于印發強化危險廢物監管和利用處置能力改革實施方案的通知》(國辦函[2021] 47號)、《關于印發<長江三角洲區域固廢危廢利用處置“白名單”和“黑名單”制定規則及運行機制(試行)>的函》，經企業申報、各市審查推薦，擬公布浙江省危險廢物利用處置“白名單(第一批)”企業，列入“白名單”企業接收長江三角洲地區危險廢物的，可按規定執行跨省轉移豁免政策?，F將擬列入“白名單(第一批)”企業公示如下: </a> </p><hr class="e_line-16 s_line" /></div> </div></div> </div> <div class="p_page"> <div 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