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<div class="cbox-1-0 p_item"><div class="e_container-6 s_layout"> <div class="cbox-6-0 p_item"><h1 class="e_h1-10 s_subtitle"> 化工廢料中丙烯三聚四聚催化劑的選擇性 </h1><div class="e_container-3 s_layout"> <div class="cbox-3-0 p_item"><p class="e_text-5 s_body"> 發布時間 </p></div> <div class="cbox-3-1 p_item"><P class="e_timeFormat-4 s_title">2022-06-29 17:38</P></div> </div><div class="e_richText-11 s_title"> <p> <strong>化工廢料中丙烯三聚四聚催化劑的選擇性</strong></p> <p> 眾所周知，在化工原料中丙烯三、四聚物是比較重要的，目前比較完善的丙烯齊聚催化劑主要包含以下三種：固體磷酸類催化劑、固體酸類催化劑和均相催化劑。</p> <p> <strong>固體磷酸催化劑的選擇性：齊聚物低</strong><br /> 一般情況下，固體磷酸類催化劑是以硅藻土、硅酸鋁或硅溶膠為載體，共混法或浸漬法負載一定量的磷酸后，高溫煅燒獲得具備相應酸量的固體磷酸催化劑。<br /> 但是這當中固體磷酸催化劑在丙烯齊聚中占主導地位，比較常見的磷酸鹽為Cu、Ni、Ca和銨鹽。<br /> 化工原料中固體磷酸催化劑的活性來源于催化劑在運轉過程中遲緩水解釋釋放的游離磷酸，催化劑表面P2O5/H2O比的大小影響到催化劑水解速率的快慢和水解產生的游離磷酸（FPA）濃度，FPA是影響到固體磷酸催化劑活性和使用壽命的主要因素，PWR小，水解速度比較快，平衡FPA濃度大，雖說活性高，但反應器床層壓力降上升和催化劑泥化失效速度比較快。<br /> <strong>化工原料中固體磷酸催化工藝</strong></p> <p> 使用磷酸-硅藻土或磷酸-硅膠作催化劑，催化劑的表層活性高、工藝合理，但三聚、四聚物以上選擇性低、使用壽命短，在反應過程中要嚴格控制注入水的量，否則催化劑易泥化、結塊等。</p> <p> <strong>優化工藝提升選擇性</strong><br /> 化工原料中丙烯齊聚過程中裂解轉化成的低碳烯烴再加成產生的非齊聚物是低價值副產物，影響到非齊聚物選擇性的關鍵因素是反應溫度和接觸時間，伴隨著反應溫度的上升和接觸時間的增長，齊聚物裂解傾向增加，裂解產物再加成產生的非齊聚物增加。<br /> 丙烯三聚體的選擇性隨反應溫度的升高而降低，四聚體的選擇性隨反應溫度的升高而升高，丙烯三聚體的選擇性隨接觸時間的增加而降低，而四聚體選擇性隨接觸時間的增加而增加。</p> <p> <strong>化工原料中固體酸催化劑難在選擇性</strong></p> <p> </p> <p> 廢料網知道固體酸催化劑在低碳烯烴聚合制備高附加值高碳烯烴產品中具備較好活性，其中沸石分子篩因其環境友好性、可再生性和產品組成可調性等優勢。</p> </div><div class="e_container-12 s_layout"> <div class="cbox-12-0 p_item"><p class="e_text-13 s_title"> </p></div> </div><div class="e_websiteShare-8 s_list" needjs="true"> <div class="p_share" data-ename="分享容器" data-selectValue="1"></div> </div></div> </div></div> </div> <input type="hidden" name="propJson" value="{"selectValue_8":"1","h1_10":"純白色系時尚小清新","layout_12":[{}],"layout_6":[{}],"text_13":"這里是占位文字","selectList_8":[{"label":"內貿","value":"1"},{"label":"外貿","value":"2"}],"href_5":{"type":"none","value":"","target":""},"format_4":"yyyy-MM-dd hh:mm","time_4":"2021-09-15 00:00","richtext_11":"<p>We are an in-de-pen-dent 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